
General Chemistry II Sample Test bank Page 3of 18
25. The number of σ bonds in N=N is
a. 1
b. 2
c. 3
d. 4
26. The elements in an ionic compound are
held together by
a. electrostatic forces of attraction.
b. van der Waals forces
c. the spin of paired electrons.
d. the formation of hybrid orbitals.
e. an electron pair.
27. In every electrolytic and galvanic (voltaic)
cell the anode is that electrode
a. at which oxidation occurs.
b. which attracts cations.
c. at which electrons are supplied to the
solution.
d. at which reduction occurs.
28. Metal X was plated from a solution
containing cations of X. The passage of 48.25 C
deposited 31 mg of X on the cathode. What is the
mass of X (in grams) per mole of electrons?
a. 47
b. 62
c. 93
d. 186
29. In a galvanic (voltaic) cell in which the
reaction is Cd + Cu
2+
" Cu + Cd
2+
and the ions are at unit concentration (activity),
the cell potential is
Cd " Cd
2+
+ 2e
-
0.4021 V
Cu " Cu
2+
+ 2e
-
- 0.344 V
a. 0.1383 V
b. 0.4021 V
c. 0.344 V
d. 0.7461 V
e. 0.3677 V
30. In which reaction will an increase in total
pressure at constant temperature favor formation
of the products?
a. CaCO
3
(s) !" CaO(s) + CO
2
(g)
b. H
2
(g) + Cl
2
(g) !"
""
" 2HCl(g)
c. 2NO(g) + O
2
(g) !" 2NO
2
(g)
d. COCl
2
(g) !" CO(g) + Cl
2
(g)
Standard Potentials E
o
Mg" Mg
2+
+2e 2.37V
Al " Al
3+
+3e 1.66V
Zn " Zn
2+
+2e 0.76V
Fe"Fe
2+
+2e 0.44V
Cu " Cu
2+
+2e 0.34V
Ag" Ag
+
+ e -0.80V
31. Using only the metals Mg, Al, Zn, Fe, Cu
and Ag, together with their 1 M salt solutions, a
voltaic cell of the highest possible voltage would
be constructed using electrodes of these metals.
a. Mg and Ag
b. Mg and Fe
c. Zn and Cu
d. Al and Ag
e. Mg and Al
32. E = E
o
- 0.059/n log Q (Nernst equation)
[H
+
] = 1.0 M initially, P
02
= 1.0 atm
4e + O
2
(g)+4H
+
(aq)!" 2H
2
O(l) E
o
=1.23V
Based on the information above, which statement
is correct?
a. n = 1, since one mole of oxygen is being
considered.
b. Addition of base should result in an E
value, which is less than 1.23 V.
c. E is independent of the pH of the solution.
d. Q = [H
2
O]
2
[O
2
] [H
+
]
33. The equilibrium constant for the gaseous
reaction C + D !" E + 2F is 3.0 at 50
o
C. In a
2.0 L flask at 50
o
C are placed 1.0 mol of C, 1.0
mol of D, 1.0 mol of E, and 3.0 mol of F.
Initially, the reaction will
a. proceed at equal rates in both directions.
b. proceed more rapidly to form E and F.
c. proceed more rapidly to form C and D.
d. not occur in either direction.
Compound
∆G
o
f
kJ/mol
H
2
O(l) —237
H
2
O(g) —229
34. At 298 K the equilibrium constant for
H
2
(g) + ½ O
2
(g)!" H
2
O(l)
a. is larger than the Keq for
H
2
(g) + ½ O
2
(g)!" H
2
O(g)
b. will have a value of 1 0 at equilibrium.
c. cannot be computed since data on O
2
and