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©anuchem2016
Content
This e-book is a compilation of class notes (Aug 2015 -Jan 2016 Semester), some creative commons license
& public domain data.
Free e-book of Chemistry for students by students.
Molecular Structure & Bonding: VSEPR Model, Valance-Bond
Theory, Molecular Orbital Theory, Molecular Orbital of Polyatomic
Molecules.
Electrochemistry: Arrhenius theory of electrolytic dissociation,
Transport Number, Kohlrausch’s Law, Solubility Product, Redox
Reaction, Electrochemical & Concentration Cells.
Chemical & Phase Equilibria: Phase Diagram for single component
system (Water), Phase diagram for Binary Eutectic System (Copper -
Silver), Corrosion of metals in acids, Corrosion by Oxygen, Corrosion
by Metal Contact.
Reaction Dynamics: Order, Molecularity, Rate Law, Methods of
determining order of reaction (1
st
& 2
nd
Order).
Polymers & Polymerization: Monomers, Polymers, their
classification, thermoplastics & thermosetting with examples, Bio-
Polymerization, Bio-Degradable Polymerization, Preparation,
Properties & Technical Applications of PVC, PVA, Teflon, Nylon6, &
Nylon6:6, Polyester, Phenol-Formaldehyde, Urea-Formaldehyde,
Natural & Synthetic Rubber, Vulcanization of Rubber.
Photochemistry: Photo-excitation of organic molecules, Jablonski
Diagram, Laws of Photochemistry and quantum yield, some examples
of photochemical reactions, chemistry of vision and other
applications of photochemistry.
Thermochemistry: Fundamental concept of first law, work, heat,
energy and enthalpies, relation between C
v
& C
p
. Second Law:
Entropy, Free Energy, (The Helmholtz and Gibbs) and chemical
potential.
Numerical problems based on water analysis and water softening
process. Determination of hardness by complexometry, Alkalinity and
its determination and their relevant numerical problems, testing of
lubricating oils, viscosity and viscosity index, flash & fire point, cloud
& pour point, Aniline Point, Carbon Residue, Steam-emulsion
number, Neutralization number, Saponification number.